(a) Mention three features of results of the photoelectric experiment which cannot be explained using the wave theory of light.
Instantaneous emission of electrons – According to wave theory, energy is spread over the wavefront so electrons should take time to accumulate enough energy. However, photoemission is instantaneous.
Existence of threshold frequency – Wave theory predicts that any frequency of light should eventually eject electrons if the intensity is high enough, but in reality, photoemission only occurs above a specific frequency.
Dependence of kinetic energy on frequency – The kinetic energy of emitted electrons depends on light frequency, not intensity, contradicting wave theory.
(b) Robert Millikan found the slope of the cut-off voltage vs. frequency plot to be 4.12 × 10–15 Vs. Calculate the value of Planck's constant
From Einstein's photoelectric equation:
\(ev_0 = hf - f\)
where e is charge of an electron, V0 is stopping potential, and h is Planck's constant.
Slope of V0 vs. f graph \(= \frac{h}{e}\)
Given:
\(\frac{h}{e} = 4.12 \times 10^{-15}\) Vs
Since e = 1.6 × 10–19 C
h = (4.12 × 10–15) × (1.6 × 10–19)
h = 6.592 × 10–34 Js