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Match List-I with List-II and select the correct option:

List-I (Solution) List-II (Properties)
(A) Benzene + Toluene (P) Show +ve deviation
(B) \(\text{Aniline} \ + \ CH_3COOH\) (Q) \(\Delta V_{mix} = 0\)
(C) Water + ethanol (R) \(\Delta H_{mix} = -ve\)
(D) \(\text{Acetone }+ \ CHCl_3\) (S) Form minimum boiling Azeotrope

(1) \(A \rightarrow Q; \ B \rightarrow R; \ C \rightarrow P, S; \ D \rightarrow R\)

(2) \(A \rightarrow B; \ B \rightarrow Q; \ C \rightarrow P, S; \ D \rightarrow R\)

(3) \(A \rightarrow Q; \ B \rightarrow P, S; \ C \rightarrow R; \ D \rightarrow P\)

(4) \(A \rightarrow P; \ B \rightarrow S; \ C \rightarrow P; \ D \rightarrow R\)

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1 Answer

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by (44.1k points)

Correct option is:  (1) \(A \rightarrow Q; \ B \rightarrow R; \ C \rightarrow P, S; \ D \rightarrow R\)

(A) \(\text{Benzene + Toleune} \Rightarrow \text{Ideal solution}\ (\Delta V_{mix} = 0)\)

(B) \(\text{Aniline + CH_3COOH} \Rightarrow \text{Negative deviation}\ (\Delta H_{mix} = \text{negative})\)

(C) \(\text{Water + ethanol} \Rightarrow \text{Positive deviation (Form minimum boiling Azeotrope)}. \)

(D) \(\text{Acetone + CHCl_3} \Rightarrow \underset{(\Delta H_{mix} = \text{negative})}{\text{Negative deviation}}\)

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