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ago in Chemistry by (45.5k points)

Calculate the molality and mole fraction of the solute in aqueous solution containing 3.0 gm of urea per 250 gm of water (Mol. wt. of urea = 60).

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ago by (45.6k points)

Wt. of solute (urea) dissolved= 3.0 gm 

Wt. of the solvent (water) = 250 gm 

Mol. wt. of the solute = 60

Calculation of molality 

3.0 gm of the solute \(= \frac{3.0}{60}\) moles = 0.05 moles

Thus 250 gm of the solvent contain = 0.05 moles of solute

\(\therefore\) 1000 gm of the solvent contain \( = \frac{0.5 \times 1000}{250} = 0.2\ \text{moles}\)

Hence molality of the solution  = 0.2 m

In short,

Molality = No. of moles of solute / 1000 g of solvent

\(\therefore \)  Molality = \(\frac{3/60}{250} \times 1000 = \) 0.2 m

Calculation of mole fraction

3.0 gm of solute = 3/60 moles = 0.05 moles

250 gm of water \(= \frac{250}{18}\) moles = 13.94 moles

\(\therefore \) Mole fraction of the solute \(= \frac{0.05 }{0.05 + 13.94} = \frac{0.05}{13.99} = \) 0.00357

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