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Explain why are cations smaller and anions larger in size than their parent atoms?

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(a) The cations are smaller than their parent atoms due to the following reasons: 

Disappearance of the valence shell. Increase of effective nuclear charge 

(b) The anions are larger than their parent atoms due to the following reason:

 An increase in the number of electrons in the valence shell reduces the effective nuclear charge due to greater mutual shielding by the electrons. As a result, electron cloud expands, i.e., the ionic radius increases. 

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