For the given reaction,
N2(g) + 3H2(g) ⟶ 2NH3(g)
Enthalpy of reaction (ΔrH0) = –92.4 kJ mol–1
N2(g) + H2(g) ⟶ NH3(g)
Hence, standard enthalpy of NH3 is equal to the 1/2 ΔrH0
As, ΔrH0 = –92.4 kJ mol–1
∴ Standard enthalpy of NH3 = \(\frac{-92.4}{2}\)
⇒ Standard enthalpy of NH3 = −46.2 kJ mol−1