Experimentally it is verified that force on any charge due to a number of other charges is the vector sum of all the forces on that charge due to the other charges, taken one at a time. The individual forces are unaffected due to the presence of other charges. This is termed as the principle of superposition.
Consider a system of three charges q1, q2 and q3, as shown in Fig (a).

The force on one charge, say q1, due to two other charges q2, q3 can therefore be obtained by performing a vector addition of the forces due to each one of these charges. Thus, if the force on q1 due to q2 is denoted by F12, F12 is given by following Eqn. even though other charges are present.

In the same way, the force on q1 due to q3, denoted by F13, is given by

which again is the Coulomb force on q1 due to q3, even though other charge q2 is present. Thus the total force F1 on q1 due to the two charges q2 and q3 is given as

The above calculation of force can be generalised to a system of charges more than three as shown in Fig (b). Then,

The vector sum is obtained as usual by the parallelogram law of addition of vectors. All of electrostatics is basically a consequence of Coulomb’s law and the superposition principle.