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BCl3 is a planar molecule whereas NCl3 is pyramidal because 

(a) BCl3 has no lone pair of electrons but NCl3 has a lone pair of electrons 

(b) B—Cl bond is more polar than N—Cl bond

(c) Nitrogen atom is smaller than boron atom 

(d) N—Cl bond is more covalent than B—Cl bond

1 Answer

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Best answer

Correct option: (a) BCl3 has no lone pair of electrons but NCl3 has a lone pair of electrons

Explanation:

In BCl3 there is sp2 hybridisation (planar) in NCl3 hybridisation is sp3 hence shape is pyramidal 

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