Correct option (b) 6 μF, 180 μC
Explanation:
The given circuit can be modified as The equivalent capacitance of C2 and C3 is

Since, C1 and C′ are in series, therefore, charge on C1 and C′ will be same
i.e. q = CAB × V
= 6 × 90 = 540 μC
Now the potential on 6 μF and 12 μF are same,

Hence, charge on 6 μF capacitor is
q6 = 30 × 6 = 180 μC