Correct Answer is: (b) 3T/8
For the particle starting from A,
x1 = a cos ωt.
For the particle starting from O' and moving to the left,
x2 = -a sin ωt.
The particles will cross when
x1 = x2 or -a sin ωt = a cos ωt
or tan ωt = -1
or ωt = 3π/4
or (2π/T) t = 3π/4
or t = 3T/8.