Dispersion. Dispersion is splitting of white light into its constituent colours.
Dispersive Power:
Consider a beam of white light passes through a prism; It gets dispersed into its constituent colours. Let δv , δR are the angles of deviation for violet and red light. Let nv and nR are the refractive indices for the violet and red light respectively.

The refractive index of the material of a prism is given by the equation

Here A is the angle of the prism and D is the angle of minimum deviation. If the angle of prism is small of the order of 10° , the prism is said to be a small angle prism. When rays of light pass through such prisms, the angle of deviation also becomes small. If A be the angle of a small angle prism and 5 the angle of deviation then the prism formula becomes.
n = \( {\frac{sin {\frac{A+δ}{2}}}{sin {\frac{A}{2}}}}\)……… (1)
For small angles of A and δm
\(sin(\frac{A + δ}{2})\) ≈ \(\frac{A+δ}{2}\)……. (2)
sin(\(\frac{A}{2}\))≈ (\(\frac{A}{2}\))…… (3)
∴ n = \(\frac{\frac{A + δ}{2}}{\frac{A}{2}}\) = \(\frac{A+δ}{A}\) = I + \(\frac{δ}{A}\)
Further simplifying, δ/A = n – 1
δ = (n – 1) A ……. (4)
When white light enters the prism, the deviation is different for different colours. Thus, the refractive index is also different for different colours.
For Violet light, δv = (nv – 1)A …(5)
For Red light, δR = (nR – 1) …(6)
As, angle of deviation for violet colour δv is greater than angle of deviation for red colour δR , the refractive index for violet colour nv is greater than the refractive index for red colour nR . Subtracting δv from δR we get,
δv – δR = (nv – nR )A ….. (7)
The term (δv – δR ) is the angular separation between the two extreme colours (violet and red) in the spectrum is called the angular dispersion. Clearly, the angular dispersion produced by a prism depends upon.
1. Angle of the prism
2. Nature of the material of the prism.
If we take 8 is the angle of deviation for any middly ray (green or yellow) and n the corresponding refractive index. Then,
8 = (n – 1) A … (8)
Dispersive power (ω) is the ability of the material of the prism to cause dispersion. It is defined as the ratio of the angular dispersion for the extreme colours to the deviation for any mean colour. Dispersive power (ω),

Substituting for (δv -δR )and (δ),
ω = \(\frac{n_v -n_R}{n-1}\) ……. (10)
Dispersive power is a dimensionless quality. It has no unit. Dispersive power is always positive. The dispersive power of a prism depends only on the nature of material of the prism and it is independent of the angle of the prism.