1. Initial rate of a first order reaction
= k C
= 1 x 10-2 x 1.0
= 1 x 10-2mol L-1 s-1
2. Concentration after 60 seconds is calculated by applying the first order kinetic equation,

Rate of reaction after 1 minute
= k x C
= 1x 10-2 x 0.5489
5.489 x 10-3 mol L-1 s-1