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Consider a first order gas phase decomposition reaction given below :

A(g) → B(g) + C(g)

The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total pressure of the system increased by x units and became ‘pt

The rate constant k for the reaction is given as _________.

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(ii) K = 2.303/t log(P1/P1 - x)

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