Plants like sugarcane, maize shows C4 pathway for the CO2 fixation during the photosynthesis to overcome the problem of photorespiration which is energy consuming process. These plants have kranz anatomy. In kranz anatomy, the mesophyll is undifferentiated and its cells occur in concentric layers around vascular bundles. Vascular bundles are surrounded by large sized bundle sheath cells. The choloroplast of mesophyll cells are smaller and perform light reaction of photosynthesis and also possess PEPcase for the CO2 fixation.
The first stable product of C4 pathway is oxalo-acetic acid.
The enzyme responsible for the fixation of atmospheric CO2 is PEP Carboxylase (Phosphoenol Pyruvate Carboxylase).