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A hot air balloon is a sphere of radius 8 m. the air inside is at a temperature of 60°C. how large a mass can the balloon lift when the outside temperature is 20°C? (Assume air is an ideal gas, R = 8.314 J mol-1 K-1 , 1 atm. = 1.013 × 103 Pa; the membrane tension is 5 Nm-1.)

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Let the pressure inside the balloon be and the outside pressure be P0

Pi − P0\(\frac{2T}{r}\)

[T = Surface Tension, r = radius balloon]

Considering the air to be an ideal gas

PiV = niRTi

Where, V is the volume of the air inside the balloon, ni is the number of moles inside and Ti is the temperature inside, and P0V = n0RT0 where V is the volume of the air displaced and nis the number of moles displaced and T0 is the temperature outside.

So, ni = \(\frac{P_{i}V}{RT_i}=\frac{M_{i}}{M_A}\)

Where Mi is the mass of the air inside and MA is the molar mass of the air and n0\(\frac{P_0V}{RT_0}=\frac{M_0}{M_A}\) where M0 is the mass of air outside that has been displaced. If W is the load it can raise, then

W + Mig = M0g

Or W = M0g − Mig

In atmospheric air, 21% O2 and 79% N2 is present.

∴ Molar mass of air

MA = 0.21 × 32 + 0.79 × 28 = 28.84 g

∴ Weight raised by balloon

or W = \(\frac{M_AV}{R}(\frac{P_0}{T_0}-\frac{P_i}{T_i})\)g        here, P0 = Pi

= \(\frac{0.02884× \frac{4}{3}π×8^3}{8.314}\) × 1.013 × 10(\(\frac{1}{293} − \frac{1} {333}\)) × 9.8 N

= 3044.2 N

Therefore, Mass lifted by balloon = \(\frac{W}{g}\)

\(\frac{3044.2\, N}{9.8\frac{m}{s^2}}\)

= 310.6 Kg

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