1. It is the isomerism which arises due to different alkyl chains on either side of the functional group in the molecule.
e.g. Methoxy propane(CH3OC3H7) and ethoxyethane (C2H5OC2H5) are metamers.
2. Free radicals are highly reactive species containing unpaired electrons. They are formed by homolytic cleavage of covalent bond.
e.g. H3