Yes, the major arcs corresponding to congruent chords are congruent.

Proof:
In ∆POQ and ∆ROS,
seg OP ≅ seg OR [Radii of the same circle]
seg OQ ≅ seg OS [Radii of the same circle]
seg PQ ≅ seg RS [Given]
∴ ∆POQ ≅ ∆ROS [SSS test of congruence]
∴ ∠POQ ≅ ∠SOR (i) [c.a.c.t]
[ m(arc PMQ) = ∠POQ (ii)
m(arc RNS) = ∠SOR ] (iii) [Definition of measure of minor arc]
∴ m(arc PMQ) = m(arc RNS)
m(minor arc) = 360° – m(major arc) (iv) [From (i), (ii) and (iii)]
m(arc PMQ) = 360° – m(arc PXQ) (v)
and m(arc RNS) = 360° – m(arc RXS) (vi)
∴ 360°- m(arc PXQ) = 360°- m(arc RXS) [From (iv), (v) and (vi)]
∴ m(arc PXQ) = m(arc RXS)