Let OP intersect chord AB at point C.
To prove : AC = BC.
Proof : In ΔPCA and ΔPCB
PA = PB (tangents at circle from external point P.)
PC = PC (common side)
∠APC = ∠BPC [∵ tangents PA and PB, make equal angle with OP]
by SAS congruence,
ΔPCA = ΔPCB
⇒ AC = BC
Hence, OP bisects line segment AB.